SPE Journal
Volume 14, Number 3, September 2009, pp. 472-476

SPE-112976-PA

Pore-Level Examination of Gel Destruction During Oil Flow

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DOI  More information 10.2118/112976-PA http://dx.doi.org/10.2118/112976-PA

Citation

  • Seright, R.S., Lindquist, W.B., and Cai, R. 2009. Pore-Level Examination of Gel Destruction During Oil Flow. SPE J.  14 (3): 472-476. SPE-112976-PA. doi: 10.2118/112976-PA.

Discipline Categories

  • 6 Reservoir Description and Dynamics
  • 6.4 Primary and Enhanced Recovery Processes
  • 6.8 Fundamental Research in Reservoir Description and Dynamics
  • 5.5 Oilfield Chemistry
  • 5.3 Production Enhancement

Keywords

  • disproportionate permeability reduction, X-ray computed microtomography, water shutoff, gels; flow in porous media

Summary

Pore-scale X-ray computed microtomography (XMT) images were obtained at a variety of oil (hexadecane) throughput values after gel placement in cores [involving a pore-filling Cr(III)-acetate-hydrolyzed polyacrylamide (HPAM) gel]. For each pore in our image volume, we followed oil and water saturations as a function of oil throughput. These studies were performed both in water-wet Berea sandstone and in hydrophobic porous polyethylene cores. In hydrophobic porous polyethylene, oil saturations increased and gel was destroyed (presumably dehydrated) quite quickly in the smallest pores. Also, oil saturations increased and gel was destroyed quickly in the largest pores. In contrast, oil saturations rose much more gradually for the most common or intermediate-size pores (around 10−4 mm3). The minimum in oil saturation vs. pore size may result from a balance between gel dehydration by oil film growth vs. gel extrusion.

In contrast, in water-wet Berea sandstone, increases in oil saturation occurred evenly over all pore sizes (10−6 to 0.02 mm3) for all oil throughput values. Consistent with imbibition and drainage studies performed before gel placement, oil apparently had equal access to Berea pores of all sizes and, thus, uniformly dehydrated gel in pores of all sizes. Gel extrusion did not appear to be significant in the Berea pores.

Introduction

An ability of gels to reduce permeability to water much more than that to oil is critical for successful applications of gel treatments in production wells if hydrocarbon zones are not protected during gel placement (Liang et al. 1993; Sydansk and Seright 2007). If gelant penetrates into an oil zone and gel forms, some time will be required before the oil penetrates through the gel bank and significant restoration of permeability to oil can occur (Seright 2006, 2009). The dependence of permeability on oil throughput determines how long it takes for a production well to restore productivity after a gel treatment.

In our previous work, XMT was used to establish why pore-filling Cr(III)-acetate-HPAM gels reduced permeability to water much more than to oil. Our results suggest that permeability to water was reduced to low values because water must flow through gel itself, whereas oil pressing on the gel in a porous rock forced pathways by dehydration—leading to relatively high permeability to oil. Those studies involved obtaining 3D pore-level X-ray images at the saturation endpoints (e.g., after forcing 20 pore volumes (PV) of oil or water through the core following gel placement). To understand the rate of restoration of permeability to oil after a gel treatment, we are interested in how the gel dehydration process progresses as a function of oil throughput. This study uses XMT to understand the throughput dependence of oil permeability after gel placement.

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History

  • Original manuscript received: 8 February 2008
  • Meeting paper published: 20 April 2008
  • Revised manuscript received: 26 June 2008
  • Manuscript approved: 21 August 2008
  • Published online: 16 July 2009
  • Version of record: 28 September 2009