SPE Journal
Volume 16, Number 1, March 2011, pp. 65-77

SPE-115961-PA

Effect of Diffusion on Dispersion

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DOI  More information 10.2118/115961-PA http://dx.doi.org/10.2118/115961-PA

Citation

  • Jha, R.K., Bryant, S.L., and Lake, L.W. 2011. Effect of Diffusion on Dispersion. SPE J.  16 (1): 65-77. SPE-115961-PA. doi: 10.2118/115961-PA.

Discipline Categories

  • 6.3.1 Flow in Porous Media
  • 6.4.7 Miscible Methods

Keywords

  • Fickian behavior, Peclet number

Summary

It is known that dispersion in porous media results from an interaction between convective spreading and diffusion. However, the nature and implications of these interactions are not well understood. Dispersion coefficients obtained from averaged cup-mixing concentration histories have contributions of convective spreading and diffusion lumped together. We decouple the contributions of convective spreading and diffusion in core-scale dispersion and systematically investigate interaction between the two in detail. We explain phenomena giving rise to important experimental observations such as Fickian behavior of core-scale dispersion and power-law dependence of dispersion coefficient on Péclet number.

We track movement of a swarm of solute particles through a physically representative network model. A physically representative network model preserves the geometry and topology of the pore space and spatial correlation in flow properties. We developed deterministic rules to trace paths of solute particles through the network. These rules yield flow streamlines through the network comparable to those obtained from a full solution of Stokes' equation. Paths of all solute particles are deterministically known in the absence of diffusion. Thus, we can explicitly investigate purely convective spreading by tracking the movement of solute particles on these streamlines.

Then, we superimpose diffusion and study dispersion in terms of interaction between convective spreading and diffusion for a wide range of Péclet numbers. This approach invokes no arbitrary parameters, enabling a rigorous validation of the physical origin of core-scale dispersion. In this way, we obtain an unequivocal, quantitative assessment of the roles of convective spreading and diffusion in hydrodynamic dispersion in flow through porous media.

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History

  • Original manuscript received: 8 July 2008
  • Meeting paper published: 22 September 2008
  • Revised manuscript received: 11 February 2010
  • Manuscript approved: 4 May 2010
  • Published online: 4 October 2010
  • Version of record: 15 March 2011