SPE Journal
Volume 18,
Number 2,
April 2013,
pp. 331-344
Summary
In certain high-pressure and low-temperature reservoirs, the density of
CO2 may be substantially higher than the oil density. Upon mixing of
CO2 and oil, a gas phase with a high content of methane
(C1) may also appear. When the C1 content is high, this
gas phase may have a lower density than the oil. In relation to this
phenomenon, we have conducted three comprehensive experiments studying
CO2 injection from the top and bottom of a vertical core and
injection in a horizontal core. The injection rate is 1 PV/day. This low rate
allows the study of diffusion. The core diameter used in this work is 3.8 cm
and the length is 27.3 cm. The tests are conducted at a pressure of 441 bar and
a temperature of 60°C. At 2.6 hydrocarbon pore volume injection (PVI), the
coreflood results give a recovery of 98% for bottom injection, 84% for top
injection, and 92% for horizontal injection. We have also conducted an
extensive set of measurements to determine swelling, viscosity, and density for
the calibration of an equation of state. We simulate the experiments using a
state-of-the-art higher-order finite-element three-phase compositional model.
The simulations suggest that the endpoint relative permeability of the
CO2-rich phase may be lower than the oil phase. The results also
show that Fickian diffusion should be taken into account, but that the
diffusion coefficients are reduced, because the CO2/oil mixtures are
in the near-critical region for much of the injection. Even for a horizontal
core there is a considerable gravity effect. One main conclusion is that there
may be vast differences between CO2 injection in a 1D slim tube and
in a core where there may be a 2D flow. A related conclusion is that analysis
of CO2 coreflooding may provide important parameters for field-scale
problems.
© 2013. Society of Petroleum Engineers
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History
- Original manuscript received:
2 May 2011
- Meeting paper published:
4 October 2009
- Revised manuscript received:
1 November 2011
- Manuscript approved:
28 March 2012
- Published online:
31 January 2013
- Version of record:
5 April 2013